Japanese superstar slumped to a 7-6 (7/4), 6-2 defeat to 39th-ranked Yulia Putintseva of Kazakhstan who had defeated the world number two on grass in Birmingham two weeks ago.
The loss came as a crushing blow to the US Open and Australian Open champion who cut short her post match press conference.
Djokovic, chasing a 16th career major, will face Denis Kudla of the United States for a place in the last 32.
Many refugees have been traumatized, providing accounts of rape, mass killings and razing of villages.
Nearly 200 homes and businesses reported hail damage, and at least 50 vehicles were swept away by the deluge of ice in hilly areas, some buried under piles of pellets.
The United States carried out several strikes in northwestern Syria, but they appeared to have petered out since 2017.
The hunts come after Japan decided to withdraw from the International Whaling Commission, a move slammed by activists and anti-whaling countries but welcomed by Japanese whaling communities.
The mineral train belonged to the Sapro mining company, and had departed from Mayoko, some 300 kilometres (186 miles) northeast of Pointe-Noire, where Sapro excavates iron ore.
The three brothers had hired wedding planning firm E-Factors to organise their sons' lavish nuptials last month at Auli, a pristine ski resort ringed by the Nanda Devi mountain range in northern Uttarakhand state.
Nearly 150 people drowned, the vast majority of them men, in Poland and neighbouring Lithuania in June as temperatures soared to record highs, officials said on Monday.
As climate change worsens, growing heat stress on workers in agriculture and other sectors will cause a productivity loss equal to 80 million full-time jobs over the next decade, the UN warned Monday.
A 3,000-year-old head sculpture of an eternally-young Tutankhamun -- the Egyptian pharaoh known as King Tut -- goes under the hammer this week in London despite an outcry from Cairo.
Argentinian cartoonist Guillermo Mordillo, known for drawing characters with bulbous noses, has died in Spain aged 86, his representatives said Monday. Mordillo's work appeared in top French magazines such as Paris-Match and Marie Claire.
Central Paris meanwhile went further by also banning diesel cars, trucks and motorbikes aged 13 years and over -- a move aimed at cleaning up the air in a city that is regularly shrouded in smog.
The unemployment rate in the eurozone dropped to 7.5 percent in May, its lowest level since July 2008, data showed Monday, despite mounting concerns that global trade wars could cool already tepid economic growth.
Officials in northern Cyprus said on Monday that a suspected Russian missile had exploded overnight on the divided island during an aerial raid in Syria.
For almost 30 years they passed as quirky eccentrics, diligently setting up their insect traps in the Rhine countryside to collect tens of millions of bugs and creepy crawlers.
Barcelona midfielder Denis Suarez has agreed to move back to his boyhood club Celta Vigo on a four-year deal, the Spanish champions said.
Recent years have seen a surge in grain-free dog and cat foods, as increasing numbers of pet owners cast aside kibble packed with cheap corn, wheat and barley fillers for what they believe is a healthier alternative.
Japan said on Monday it will tighten regulations on the export to South Korea of several chemicals used in chip and smartphone production amid a row with Seoul on wartime forced labour.
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